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A) Chemoenzymatic synthesis of disaccharide building block and controlled chemoenzymatic synthesis of size-defined polysaccharides by Pd2,6ST-catalyzed block transfer of disaccharide building blocks. B) Chemoenzymatic synthetic route of asymmetrically multi-antennary glycans using selected O-acetylated acceptor. C) Chemoenzymatic synthesis of modules with selected O-acetylation for N-glycan assembly.
