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A) Molecular structure of Ag8 cluster, Ag12 cluster and tppe ligand. B) Single net of 1⊃DMAC framework viewed along the c‐axis, the DMAC molecules are omitted for clarity. C) Two fold interpenetrated topology of 1⊃DMAC. D) Enlargement of the circled section in (B): an octahedral cage surrounded by four tppe ligands and two Ag8 clusters.
