. Author manuscript; available in PMC: 2019 Jan 24.

Published in final edited form as: J Am Chem Soc. 2018 Nov 9;140(46):15621–15625. doi: 10.1021/jacs.8b10288

Table 2.

Organolithium Scope

Isolated yields of analytically pure material.

Enantiomeric ratio determined by chiral stationary phase NP-HPLC or SFC.

2e generated in the presence of 1a.

Conditions for oxidation of 6 to 7: NaOH/H₂O₂/THF, 0 °C.