Table 3. Results from Numerical Solutions to the Rate Law Implied by Scheme 1B.

Re126WWCuI	Inputs: k3–1 = 60 ns; k4–1 = 1.15 μs; k9–1 = 120 μs
elementary rate constants	k1–1 /ps	K1	k5–1 /ns	K2	k7–1 /ns	k8–1 /ns
	400–475	1.5–2.0	7–9	0.55–0.75	125–750	60–90
yield and empirical time constants	τ1 /ps	τ2 /ns	τ3 /ns	τ4 /μs	Φ124/Φ126
	260–280	3.5–4	70–90	120	2.0–2.2

Re126WWCuII	Inputs: k3–1 = 60 ns;k4–1 = 1.15 μs; k8 = k9 = 0
elementary rate constants	k1–1 /ps	K1	k5–1 /ns	K2	k7–1 /ns
	375–425	2.25–3.25	9–21	0.25–0.75	100–350
empirical time constants	τ1 /ps	τ2 /ns	τ3 /ns
	280–300	3.5–4.5	70–90

Re126WFCuI	Inputs: k4–1 = 1.15 μs; k5 = k6 = k8 = k9 = 0
elementary rate constants	k1–1 /ps	K1	k3–1 /ns
	234	5.7	61 ns
empirical time constants	τ1 /ps	τ2 /ns
	200	71