Table 4. Retention time, UV spectrum, mass, molecular formula, chemical class and plants species in which compounds were detected of active peaks with relative intensity of masses higher than 20000 and were positively correlated to EC90.
| Peak |
Ret (min) |
UV | [M-H]- | Molecular formula | MS/MS | Class | Compounds | Plants |
| 1 | 1.1 | --- | 665.2114 | --- | --- | Unknown | Unknown | H_brevi; A_latis; L_canes; V_cymos; H_mutab; M_latif |
| 2 | 2.0 | --- | 389.1076 | C16H22O11 | 389: 227 (C10H11O6); 209 (C10H9O5); 183 (C9H11O4) | Iridoid | Hexosyl iridoid derivative | D_kuntz |
| 3 | 3.0 | --- | 389.1080 | C16H22O11 | 389: 227 (C10H11O6); 209 (C10H9O5); 183 (C9H11O4) | Iridoid | Hexosyl iridoid derivative | D_kuntz |
| 4 | 4.7 | --- | 363.1297 | C15H23O10 | 363:201(C9H13O5) | Iridoid | Hexosyl iridoid derivative | A_hirta |
| 5 | 6.5 | --- | 345.1191 | C15H22O9 | 345: 207 (C11H11O4); 189 (C11H9O3); 183 (C9H11O4) | Iridoid | Hexosyl iridoid derivative | A_hirta |
| 6 | 6.6 | --- | 345.1190 | C15H22O9 | 345: 207 (C11H11O4); 189 (C11H9O3); 183 (C9H11O4) | Iridoid | Hexosyl iridoid derivative | A_hirta |
| 7 | 9.0 | 301/322 | 353.0891 | C16H18O9 | 353: 191 (C7H11O6) | Phenylpropanoid | chlorogenic acid | I_chili; A_latis; S_hispi; D_kuntz; C_punct; V_cymos; M_latif |
| 8 | 10.4 | --- | 413.1085 | C18H22O11 | 413: 371 (C16H19O10); 251 (C12H11O6); 191 (C10H7O4) | Iridoid | Asperuloside | D_kuntz |
| 9 | 11.5 | --- | 405.1401 | C17H26O11 | 405: 387 (C17H23O10); 243 (C11H15O6); 225 (C11H13O5) | Iridoid | Sanshiside methyl ester | L_canes |
| 10 | 11.5 | 268 | 633.0719 | C27H22O18 | 633: 463 (C20H15O13); 301 (C14H5O8); 275 (C13H7O7) | Hydrolized tannin | Corilagin | S_hispi |
| 11 | 12.6 | 268 | 951.0787 | C41H28O27 | 951: 933(C41H25O26); 765 (C34H21O21); 463 (C20H15O13); 301 (C14H5O8); 275 (C13H7O7) | Hydrolized tannin | Geraniin | S_hispi |
| 12 | 12.8 | 301/327 | 515.1180 | C25H24O12 | 515: 191 (C7H11O6); 179 (C9H7O4) | Phenylpropanoid | 1,3 Dicaffeoylquinic | I_chili; A_latis |
| 13 | 16.0 | 281/344 | 463.0859 | C21H20O12 | 463: 301 (C15H9O7) | Flavonoid | Isoquercitrin | A_hirta |
| 14 | 16.4 | 282 | 463.0900 | C21H20O12 | --- | Flavonoid | Flavanone derivative | A_hirta; C_punct |
| Peak | Ret (min) |
UV | [M-H]- | Molecular formula | MS/MS | Class | Compounds | Plants |
| 15 | 17.4 | 270/345 | 739.2096 | C33H39O19 | --- | Flavonoid | Flavonol-hexosyl-dideoxyhexosyl | T_form; V_cymos |
| 16 | 17.9 | 270/344 | 477.1059 | C22H22O12 | 477: 314 (C16H10O7); 299 (C15H7O7) | Flavonoid | Isorhamnetin-O-glucoside | A_hirta |
| 17 | 18.0 | 270/346 | 461.0740 | C21H18O12 | 461: 285 (C15H9O6) | Flavonoid | Kaempferol-O-glucuronide | L_canes; A_hirta; C_punct; V_cymos |
| 18 | 19.1 | 296/327 | 623.1958 | C29H36O15 | 623: 461 (C20H29O12); 315 (C14H19O8); 179 (C9H7O4); 161 (C9H5O3) | Phenylpropanoid | Verbascosideo | L_canes; H_serra |
| 19 | 19.1 | 301/327 | 515.1190 | C25H24O12 | 515: 191 (C7H11O6); 179 (C9H7O4); 173 (C7H9O5) | Phenylpropanoid | 3,4 Dicaffeoylquinic | I_chili; A_latis; C_punct; V_cymos |
| 20 | 19.8 | 301/327 | 515.1193 | C25H24O12 | 515: 191 (C7H11O6); 179 (C9H7O4) | Phenylpropanoid | 3,5 Dicaffeoylquinic | I_chili; A_latis; C_punct; V_cymos |
| 21 | 19.9 | 283/343 | 593.1489 | C27H30O15 | 593: 285 (C15H9O6) | Flavonoid | Kaempferol-O-rutinoside | I_chili; S_hispi; D_kuntz; H_mutab; H_brevi; C_acule |
| 22 | 20.0 | 270 | 419.0970 | C20H20O10 | 419: 179 (C9H7O4) | Unknown | Unknown | H_serra |
| 23 | 20.3 | 290/327 | 623.1973 | C29H36O15 | 623: 461 (C20H29O12); 315 (C14H19O8); 179 (C9H7O4); 161 (C9H5O3) | Phenylpropanoid | Isoverbascosideo | L_canes |
| 24 | 20.5 | 266/338 | 445.0753 | C21H18O11 | 445: 269 (C15H9O5) | Flavonoid | Apigenin-O-glucuronide | L_canes |
| Peak | Ret (min) |
UV | [M-H]- | Molecular formula | MS/MS | Class | Compounds | Plants |
| 25 | 20.6 | 292/326 | 359.0760 | C18H16O8 | 359: 197 (C9H9O5); 179 (C9H7O4); 161 (C9H5O3) | Phenylpropanoid | Rosmarinic acid | H_mutab; H_brevi |
| 26 | 23.5 | 300/326 | 307.0462 | C14H12O8 | --- | Phenylpropanoid | Unknown | E_panic |
| 27 | 23.6 | 287/330 | 717.1420 | C36H30O16 | 717: 519 (C27H19O11); 339 (C18H11O7); 321 (C18H9O6) | Unknown | Unknown | H_mutab; H_brevi |
| 28 | 28.2 | --- | 809.4308 | C42H66O15 | 809: 603 (C35H55O8) | Triterpene saponin | quinovic acid derivative | T_formo |
| 29 | 28.7 | 300/326 | 403.1380 | C21H24O8 | 403: 359 (C20H23O6); 241 (C12H17O5); 197 (C11H17O3); 179 (C9H7O4) | Brevipolide | Dihydro-Brevipolide C | H_brevi |
| 30 | 29.5 | 281/346 | 359.0759 | C18H16O8 | 359: 329 (C16H9O8); 301 (C15H9O7); 286 (C14H8O7); | Flavonoid | 5,6,3'-trihydroxy-3,7,4'-trimethoxyflavone | H_brevi |
| 31 | 30.4 | --- | 955.4908 | C48H76O19 | --- | Triterpene saponin | Calenduloside derivative | A_latis |
| 32 | 30.6 | --- | 793.4358 | C35H55O7 | 793:587 () | Triterpene saponin | --- | T_formo; V_cymos |
| 33 | 30.8 | 300/313 | 387.1445 | C21H24O7 | 403: 343 (C20H23O5); 241 (C12H17O5); 197 (C11H17O3); 179 (C9H7O4) | Brevipolide | Dihydro-Brevipolide F | H_brevi |
| 34 | 31.8 | --- | 955.4911 | C48H76O19 | --- | Triterpene saponin | Calenduloside H | I_chili; A_latis |
| 35 | 32.6 | --- | 939.4971 | C48H76O18 | --- | Triterpene saponin | Triterpene saponin derivative | I_chili; A_latis |
| 36 | 34.8 | --- | 793.4362 | C42H66O14 | --- | Triterpene saponin | Ladyginoside B | I_chili |
| 37 | 36.0 | --- | 777.4416 | C42H66O13 | --- | Triterpene saponin | Triterpene saponin derivative | I_chili; A_latis |