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Coreactant ECL reaction mechanism for [Ru(bpy)3]2+ and n-tripropylamine (TPrA). Oxidation of [Ru(bpy)3]2+ and TPrA at the electrode surface followed by electron transfer from oxidized TPrA to [Ru(bpy)3]2+ forms an excited state [Ru(bpy)3]2+ that then undergoes phosphorescence to decay back to the ground state. Adapted from ref (149). Copyright 2004 American Chemical Society.
