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. 2018 Nov 30;122(51):12396–12402. doi: 10.1021/acs.jpcb.8b07901

Figure 3.

Figure 3

(A) Normalized short-time self-diffusion coefficient, Dself = Ds/D0, as a function of the volume fraction ϕ. Results for the hard (HE) and attractive (ATT_E) ellipsoids are displayed, together with results for the hard (HS) and attractive (ATT_S) spheres. Ellipsoids show a lower mobility than spheres because of the larger effective hydrodynamic size. Inset: short-time self-diffusion describes the Brownian motion within the cage of neighboring particles. (B) The normalized difference between self-diffusion of ellipsoids and spheres, as obtained from theoretical predictions for hard spheres43,44 (solid black line in panel A) and polynomial guide-to-the-eyes (dashed lines in panel A).