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. 2019 Jan 22;15:194–209. doi: 10.3762/bjoc.15.19

Table 7.

Summary of the catalytic performance of precatalyst 8 present in different concentrations (80 °C, 420 min).

Entry C8:Ru Conv.a PMPsa SMPsa IPsa Sb TONc TOFd

1 6000 76.9 70.7 5.9 0.4 92 4240 16.83 × 10−2
2 9000 65.4 60.5 4.1 0.8 92 5445 21.61 × 10−2
3 10000 60.2 55.4 4.5 0.4 92 5539 21.98 × 10−2
4 15000 52.8 48.4 3.8 0.7 92 7254 28.78 × 10−2

aConversion or yield in mol %; bS (selectivity) in percent toward PMPs; cTON (turnover number) = [%PMPs × (Oct/Ru)]/100; dTOF (turnover frequency) = TON/time in s.