Skip to main content
. Author manuscript; available in PMC: 2020 Jan 30.
Published in final edited form as: J Am Chem Soc. 2019 Jan 15;141(4):1555–1567. doi: 10.1021/jacs.8b10992

Scheme 1.

Scheme 1.

Reaction mechanism for the first and rate limiting step of the stereospecific oxidation of linoleic acid catalyzed by SLO, where the hydrogen atom transfer from substrate LA to ferric hydroxide cofactor occurs by a PCET process.