Table 2.
Volatile compound | RT (min) | BR+5 Content (ng g−1 FW h−1) | BR+7 Content (ng g−1 FW h−1) | BR+10 Content (ng g−1 FW h−1) | ||||||
---|---|---|---|---|---|---|---|---|---|---|
WT | #11 | #19 | WT | #11 | #19 | WT | #11 | #19 | ||
Aldehydes | ||||||||||
trans-2-Hexenal | 4.90 | 259.65 ± 22.48 | 421.29 ± 31.71 | 331.96 ± 22.38 | 193.00 ± 32.87 | 368.42 ± 50.84 | 257.05 ± 36.45 | 219.73 ± 35.18 | 352.31 ± 25.68 | 303.40 ± 25.90 |
Hexanal | 3.66 | 77.29 ± 11.74 | 116.96 ± 22.90 | 97.84 ± 7.12 | 44.35 ± 11.82 | 89.52 ± 21.54 | 77.92 ± 5.11 | 74.98 ± 8.37 | 196.91 ± 46.12 | 128.03 ± 19.14 |
3-Hexenal | 3.62 | 33.29 ± 2.98 | 56.18 ± 3.15 | 46.63 ± 2.37 | 12.07 ± 0.96 | 42.74 ± 2.73 | 28.51 ± 2.64 | 25.33 ± 2.89 | 48.25 ± 2.19 | 39.32 ± 3.28 |
(Z)-2-Heptenal | 8.01 | 4.83 ± 0.54 | 11.46 ± 1.66 | 7.80 ± 0.61 | 6.38 ± 1.00 | 11.21 ± 1.80 | 8.86 ± 0.35 | 6.63 ± 0.52 | 14.43 ± 2.11 | 10.62 ± 0.74 |
(E,E)-2,4-Heptadienal | 9.06 | 3.85 ± 0.24 | 7.64 ± 0.73 | 6.08 ± 0.13 | 2.95 ± 0.54 | 6.43 ± 1.76 | 4.77 ± 0.19 | 6.42 ± 1.72 | 16.48 ± 1.28 | 9.01 ± 1.47 |
Heptanal | 6.55 | 2.59 ± 0.39 | 5.55 ± 0.70 | 4.97 ± 0.25 | 1.90 ± 0.52 | 4.82 ± 1.07 | 3.42 ± 0.43 | 3.16 ± 0.61 | 5.61 ± 1.75 | 4.38 ± 1.32 |
Geranial | 15.05 | 12.27 ± 2.42 | 31.05 ± 2.99 | 21.22 ± 2.96 | 47.15 ± 7.63 | 276.86 ± 44.54 | 204.11 ± 41.07 | 66.92 ± 11.91 | 252.34 ± 15.73 | 179.60 ± 31.54 |
Neral | 14.52 | ND | 6.33 ± 2.33 | 4.27 ± 1.03 | ND | 5.45 ± 0.46 | 3.18 ± 0.71 | 5.70 ± 1.37 | 22.40 ± 2.62 | 15.37 ± 1.96 |
Benzaldehyde | 7.90 | 3.49 ± 0.89 | 6.38 ± 1.63 | 4.91 ± 1.10 | 3.73 ± 0.79 | 8.70 ± 1.13 | 6.70 ± 0.68 | 4.23 ± 0.92 | 7.63 ± 1.42 | 6.46 ± 0.45 |
Alcohols | ||||||||||
6-Methyl-5-hepten-2-ol | 9.30 | 9.63 ± 2.62 | 11.04 ± 2.40 | 10.23 ± 0.43 | 19.38 ± 8.69 | 23.81 ± 2.63 | 21.54 ± 4.15 | 16.45 ± 3.52 | 27.56 ± 4.53 | 24.25 ± 2.73 |
2-Propyl-1-pentanol | 10.26 | 20.01 ± 5.13 | 10.04 ± 0.54 | 14.64 ± 2.68 | 13.82 ± 2.93 | 5.60 ± 3.16 | 8.75 ± 1.57 | 3.36 ± 1.25 | 1.91 ± 0.37 | 2.22 ± 0.75 |
Eucalyptol | 14.91 | ND | ND | ND | ND | 108.95 ± 23.39 | 70.36 ± 9.40 | ND | 85.87 ± 7.43 | 53.91 ± 5.61 |
1-Octanol | 11.23 | 4.23 ± 0.82 | 9.57 ± 1.00 | 6.20 ± 0.34 | 4.71 ± 1.16 | 10.07 ± 2.78 | 7.21 ± 0.77 | 5.16 ± 0.49 | 9.60 ± 1.30 | 6.73 ± 0.72 |
Matsutake alcohol | 8.98 | ND | ND | ND | ND | 21.52 ± 2.68 | 14.39 ± 2.82 | ND | 13.66 ± 1.27 | 7.89 ± 0.48 |
Ketones | ||||||||||
β-ionone | 18.81 | 1.66 ± 0.12 | 1.88 ± 0.43 | 1.79 ± 0.29 | 1.77 ± 0.39 | 2.86 ± 0.64 | 2.19 ± 0.91 | 1.89 ± 0.59 | 2.78 ± 0.52 | 2.32 ± 0.31 |
6-Methyl-5-h eptene-2-one | 8.96 | 64.57 ± 14.54 | 71.89 ± 18.57 | 69.16 ± 15.53 | 50.77 ± 7.89 | 58.18 ± 13.71 | 56.33 ± 12.84 | 161.80 ± 12.71 | 170.58 ± 36.07 | 165.23 ± 13.39 |
Geranylacetone | 18.27 | 8.46 ± 1.52 | 15.84 ± 2.14 | 13.73 ± 1.92 | 13.82 ± 1.15 | 39.76 ± 5.49 | 27.06 ± 1.15 | 24.37 ± 4.34 | 40.88 ± 8.84 | 31.89 ± 5.01 |
3-Nonanone | 11.49 | 2.88 ± 0.73 | 13.47 ± 2.38 | 8.18 ± 0.97 | 91.51 ± 0.40 | 202.60 ± 37.01 | 151.44 ± 22.51 | 140.37 ± 13.72 | 279.56 ± 24.59 | 216.84 ± 24.57 |
Farnesyl acetone | 24.82 | 3.27 ± 0.30 | 5.35 ± 0.28 | 4.42 ± 0.18 | 4.35 ± 0.76 | 8.42 ± 0.84 | 7.09 ± 0.92 | 4.32 ± 0.71 | 9.78 ± 2.36 | 7.47 ± 1.08 |
Esters | ||||||||||
Methyl salicylate | 13.59 | 4.75 ± 1.33 | 13.67 ± 1.07 | 11.19 ± 0.61 | 4.01 ± 1.69 | 20.95 ± 1.66 | 12.06 ± 1.06 | 2.88 ± 0.45 | 8.96 ± 0.89 | 6.97 ± 0.59 |
Geranyl acetate | 17.15 | ND | ND | ND | 6.20 ± 1.04 | 31.49 ± 8.72 | 21.33 ± 3.07 | 6.78 ± 1.73 | 33.68 ± 4.80 | 21.09 ± 2.35 |
Nerol acetate | 16.84 | ND | ND | ND | 4.65 ± 0.58 | 17.08 ± 2.55 | 10.57 ± 0.86 | 5.39 ± 1.33 | 16.32 ± 2.07 | 10.83 ± 1.61 |
α-terpineol acetate | 16.66 | ND | ND | ND | 3.82 ± 0.43 | 21.86 ± 3.01 | 13.74 ± 2.75 | 4.95 ± 0.90 | 21.79 ± 5.01 | 15.64 ± 3.53 |
2-Ethylhexyl acrylate | 14.52 | 87.61 ± 16.45 | ND | ND | 61.36 ± 20.21 | ND | ND | ND | ND | ND |
Isobutyl acetate | 4.13 | 0.34 ± 0.05 | 0.54 ± 0.08 | 0.50 ± 0.10 | 0.20 ± 0.08 | 0.78 ± 0.08 | 0.55 ± 0.07 | 0.18 ± 0.03 | 0.30 ± 0.08 | 0.29 ± 0.06 |
Terpenoids/Terpenes | ||||||||||
Linalool | 11.88 | 28.06 ± 6.20 | 134.50 ± 16.79 | 99.69 ± 6.14 | 34.47 ± 11.09 | 313.13 ± 40.92 | 234.12 ± 13.87 | 59.80 ± 13.92 | 370.44 ± 35.57 | 260.58 ± 38.45 |
Terpineol | 13.68 | 4.48 ± 0.96 | 13.61 ± 3.12 | 11.10 ± 1.87 | 6.67 ± 3.57 | 27.87 ± 3.05 | 17.77 ± 5.06 | 8.62 ± 2.00 | 19.03 ± 4.04 | 12.59 ± 2.01 |
(-)-4-Terpineol | 13.46 | 1.02 ± 0.46 | 11.08 ± 0.99 | 7.22 ± 0.47 | 16.37 ± 0.38 | 92.76 ± 14.58 | 69.05 ± 19.86 | 18.34 ± 3.24 | 63.52 ± 5.78 | 49.16 ± 8.37 |
D-Limonene | 10.36 | 9.71 ± 1.38 | 19.62 ± 4.13 | 14.77 ± 1.53 | 19.79 ± 4.63 | 60.74 ± 14.19 | 16.18 ± 5.76 | 34.08 ± 6.72 | 79.74 ± 12.15 | 74.22 ± 9.23 |
β-myrcene | 9.46 | 1.91 ± 1.05 | 4.38 ± 1.02 | 3.43 ± 1.19 | 12.53 ± 2.52 | 44.03 ± 12.17 | 25.94 ± 5.84 | 26.07 ± 2.44 | 50.97 ± 7.38 | 44.39 ± 4.12 |
Copaene | 17.39 | 10.92 ± 2.15 | 29.06 ± 5.95 | 21.38 ± 2.57 | 4.14 ± 0.93 | 38.62 ± 9.59 | 23.16 ± 4.24 | 7.20 ± 1.94 | 9.03 ± 1.23 | 7.37 ± 0.57 |
Ocimene | 10.83 | 0.46 ± 0.07 | 0.73 ± 0.50 | 0.58 ± 0.03 | 16.55 ± 2.42 | 24.04 ± 4.16 | 19.50 ± 3.43 | 14.59 ± 1.47 | 21.05 ± 3.46 | 16.23 ± 4.08 |
β-trans-ocimene | 10.57 | 0.42 ± 0.07 | 1.24 ± 0.37 | 0.87 ± 0.13 | 5.41 ± 0.47 | 18.24 ± 1.73 | 12.02 ± 1.00 | 6.28 ± 0.90 | 15.26 ± 3.26 | 11.97 ± 2.47 |
γ-terpinen | 11.05 | 0.56 ± 0.03 | 1.50 ± 0.25 | 0.92 ± 0.15 | 0.45 ± 0.25 | 7.28 ± 1.26 | 5.09 ± 0.96 | 1.45 ± 1.21 | 8.39 ± 0.60 | 6.26 ± 0.16 |
Terpilene | 10.06 | ND | ND | ND | ND | 5.71 ± 0.50 | 3.09 ± 0.35 | ND | 6.18 ± 0.53 | 3.62 ± 0.45 |
Terpinolen | 11.72 | ND | 1.12 ± 0.15 | ND | ND | 7.12 ± 2.15 | 3.21 ± 0.59 | 1.60 ± 0.23 | 11.88 ± 1.61 | 6.84 ± 1.81 |
α-phellandrene | 9.74 | ND | ND | ND | ND | 5.10 ± 0.98 | 2.97 ± 0.69 | 3.82 ± 0.58 | 6.48 ± 0.93 | 4.96 ± 0.36 |
β-cyclocitral | 14.15 | 1.02 ± 0.25 | 1.99 ± 0.23 | 1.56 ± 0.20 | 1.30 ± 0.30 | 1.84 ± 0.14 | 1.52 ± 0.35 | 1.35 ± 0.48 | 2.68 ± 0.51 | 2.08 ± 0.38 |
Note: The data are expressed as the means ± standard deviation of triplicate samples. RT retention time, ND not detectable