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(A) Kinetic resolution of (±)-8 with P2 to yield acylated (R,R)-9. (B) Desymmetrizing phosphorylation of inositol derivative 10 with P3. (C) One pot phosphorylation of (±)-8 and 10 revealed P3 favors reaction with (S,S)-8, opposite to P2. (D–F) Scheme and NMR data for peptide-mediated one-pot reactions.
