Table 1.
Polymer | Molecular Weight | LCST (°C) d | |||
---|---|---|---|---|---|
GPC | 1H NMR b | Titration c | |||
Mn a | Mw a | ||||
P(NIPAAm-co-DMAPAAm) | 17,000 | 4.4 | 11,000 | 41.9 | |
P(NIPAAm-co-DMAAm) | 15,000 | 3.5 | 13,500 | 41.7 |
a Determined by GPC using polyethylene glycol as a standard and DMF containing 10 mM LiCl as the mobile phase, b Determined by 1H NMR using CDCl3 as a solvent. c Determined by titration of the terminal carboxyl group, d Defined as the temperature at which the optical transmittance of the polymer solution was 50% of the difference between the maximum and minimum transmittances.