Table 2.
Summary of the gas-sensing performances of semiconductor metal oxides for ethanol gas.
| Order | Dimensions | Materials | Synthesis Method | Conc. (ppm) | LOD (ppm) | Temp. (°C) | τres (s) | τrec (s) | Resp. | Ref. |
|---|---|---|---|---|---|---|---|---|---|---|
| 1 | 0D | CuBi2O4 powders | polymerized complex method | 1000 | 5 | 400 | 57 | 294 | 10.4 b | [85] |
| 2 | SnO2 nanoparticles | microwave treatment | 250 | NA | 100 | 16 | 25 | 30 c | [86] | |
| 3 | 1D | Co3O4 microrods | interfacial-reaction | 100 | NA | 220 | 0.8 | 10.8 | 9.8 b | [87] |
| 4 | CuO/In2O3 nanorods | thermal evaporation and sputtering | 50 | NA | 300 | 53 | 149 | 3.82 a | [88] | |
| 5 | In2O3 microrods | hydrothermal | 100 | 1 | 300 | 15 | 20 | 18.33 a | [89] | |
| 6 | LaFeO3 nanotubes | electrospinning | 100 | NA | 160 | 2 | 4 | 9.4 b | [90] | |
| 7 | Pd/Fe2O3 nanotubes | electrospinning | 50 | 0.1 | 240 | 8 | 30 | 65.4 a | [91] | |
| 8 | ZnO nanotubes | electrodeposition and electrochemical etching | 700 | 1 | RT | 4.56 min | 1.53 min | 64.17% c | [83] | |
| 9 | LaMnO3/SnO2 nanofibers | electrospinning | 100 | NA | 260 | 6 | 34 | 20 a | [92] | |
| 10 | WO3/SnO2 nanofibers | coaxial electrospinning | 10 | NA | 280 | 18.5 | 282 | 5.09 a | [93] | |
| 11 | ZnO nanowires | solvothermal | 500 | NA | 340 | 6 | 26 | 10.68 a | [94] | |
| 12 | SnO2/Fe2O3 nanowires | VLS, hydrothermal and spin coating | 5 | NA | 300 | 100 | 300 | 3.07 a | [95] | |
| 13 | SnO2/ZnO nanowires | carbon-assisted thermal evaporation | 400 | NA | 400 | NA | NA | 128 c | [96] | |
| 14 | SnO2/ZnO nanowires | thermal evaporation and spray-coating | 100 | NA | 400 | NA | NA | 14.1a | [97] | |
| 15 | 2D | CuO films | RF sputtering | 12.5 | NA | 180 | 31 | 52 | 2.2 b | [98] |
| 16 | Pd/Ce/SnO2 films | co-precipitation | 100 | NA | 250 | 6 | 20 | 88 c | [99] | |
| 17 | NiO nanosheets | hydrothermal | 50 | 1 | 240 | 4 | 7 | 11.15 b | [100] | |
| 18 | ZnO nanosheets | hydrothermal | 50 | 1 | 330 | 15 | 12 | 83.6 a | [101] | |
| 19 | 3D | SnO2 nanoflowers | hydrothermal | 200 | 4.52 | 240 | 10 | 16 | 62.2 a | [102] |
| 20 | SnO2 nanoflowers | hydrothermal | 100 | NA | 300 | 10 | 16 | 47.29 a | [103] | |
| 21 | Au/SnO2 hierarchical structures | hydrothermal | 100 | NA | 340 | 5 | 10 | 18 a | [104] | |
| 22 | NiO hierarchical structures | hydrothermal | 400 | NA | 300 | 4 | 8 | 32 b | [105] | |
| 23 | SnO2 macropores structures | sol-gel method | 500 | NA | 240 | NA | NA | 70.94 a | [106] | |
| 24 | MoO3 microboxes | hydrothermal | 100 | 1 | 260 | 15 | 5 | 78 a | [107] | |
| 25 | SnO2 nanocubes | hydrothermal | 100 | 1 | 200 | 23 | 21 | 1670.5 a | [108] | |
| 26 | ZnSnO3 nanocubes | co-precipitation | 100 | NA | 260 | 4 | 276 | 34.1 a | [109] | |
| 27 | PdO/Zn2SnO4 octahedrons | hydrothermal and wet impregnation treatment | 100 | 0.5 | 250 | 1 | 206 | 82.3 a | [110] | |
| 28 | WO3 urchin-like structures | hydrothermal | 100 | NA | 350 | 28 | 12 | 68.56 a | [111] | |
| 29 | Co3O4 microspheres | interfacial-reaction | 100 | 1 | 220 | 0.1 | 0.7 | 38.2 b | [112] | |
| 30 | CuO microspheres | precipitation | 400 | NA | 250 | 17 | 11.9 | 5.6 b | [113] | |
| 31 | CuO microspheres | hydrothermal | 100 | NA | 200 | 2 | 8 | 390% c | [114] | |
| 32 | Fe2O3/Co3O4 microspheres | solution route | 100 | NA | 170 | 3.3 | 5.4 | 16.1 b | [115] | |
| 33 | SnO2 microspheres | ion exchange method | 200 | NA | 260 | NA | NA | 103.1 a | [116] | |
| 34 | SnO2/Fe2O3 microspheres | hydrothermal | 100 | 0.1 | 260 | 3 | 4 | 41.7 a | [117] | |
| 35 | ZnFe2O4 microspheres | solvothermal | 10 | 0.5 | 180 | 5.1 | 6.5 | 6.85 a | [118] | |
| 36 | Pt/SnO2 nanospheres | spray drying and Kirkendall diffusion | 5 | 0.25 | 325 | 1 | 1577 | 1399.9 a | [119] | |
| 37 | SnO2 nanospheres | precipitation | 200 | NA | 260 | 10 | 8 | 274.5 a | [120] | |
| 38 | SnO2 nanospheres | hydrothermal | 100 | 0.5 | 350 | 5 | NA | 10.5 a | [121] | |
| 39 | SnO2/ZnO nanospheres | self-sacrificial template | 50 | NA | 270 | 0.4 | 235 | 7.5 a | [122] | |
| 40 | ZnSnO3 nanospheres | hydrothermal | 100 | NA | 200 | 4 | 30 | 32 a | [123] | |
| 41 | Zn2SnO4 nanospheres | hydrothermal | 50 | 5 | 180 | NA | NA | 23.4 a | [124] |
Note: Conc. = concentration; LOD = limit of detection; Temp. = temperature; τres = response time; τcov = recovery time; Resp. = Response; Ref. = References; RT = room temperature; a S = Ra/Rg; b S = Rg/Ra; c S = (ΔR/Ra)*100%; d S = Ig/Ia; NA = not available.