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Heme-peroxo-copper and heme–superoxo adducts characterized by the Karlin group featuring heme plus tridentate binuclear ligand frameworks: (A) [(2L)FeIII–(O22–)–CuII]+,938 (B) [(3L)FeIII(O2•–)], and (C) [(4L)FeIII–(O22–)–CuII]+.522 See text for details.