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. Author manuscript; available in PMC: 2019 Nov 28.
Published in final edited form as: Chem Rev. 2018 Oct 29;118(22):10840ā€“11022. doi: 10.1021/acs.chemrev.8b00074

Figure 131.

Figure 131.

Surface enhanced resonance raman spectroscopy (SERRS) coupled to rotating ring-disc-electrochemistry (RRDE) developed by Sengupta and Dey, applied to synthetic heme-copper model systems developed by the Karlin group (A, B, and C). The resonance Raman data (bottom right) show the presence of a peroxidic intermediate during electrocatalytic O2 reduction. Adapted from ref 1051. Copyright 2015 American Chemical Society.