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. Author manuscript; available in PMC: 2019 Nov 28.
Published in final edited form as: Chem Rev. 2018 Oct 29;118(22):10840–11022. doi: 10.1021/acs.chemrev.8b00074

Scheme 11.

Scheme 11.

Proposed “Turn-On” Mechanism of Nucleophilic Activity of [(TPFPP)FeIII(O22−)]− upon Axial Coordination of the DMSO Solvatea

aAdapted from ref 529. Copyright 1998 American Chemical Society. See text for discussion.