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. Author manuscript; available in PMC: 2019 Nov 28.
Published in final edited form as: Chem Rev. 2018 Oct 29;118(22):10840ā€“11022. doi: 10.1021/acs.chemrev.8b00074

Scheme 15.

Scheme 15.

Differences in Formation, and Reactivity Landscapes of Five-Coordinate [(TPFPP)FeIII(OOH)] and Six-Coordinate [(OH)(TPFPP)FeIII(OOH]āˆ’ Ferric Hydroperoxo Complexes