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Formation and decay of the heme/Cu μ-peroxo species giving heme-superoxo and reduced CuI as observed by Naruta. Since the rate of formation of the superoxo is increased upon added water, a water-mediated hydrogen-bonding interaction between the tethered phenol and the superoxo ligand is postulated. R = H, MOM. Adapted with permission from ref 485. Copyright 2005 Wiley-VCH.
