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. Author manuscript; available in PMC: 2019 Nov 28.
Published in final edited form as: Chem Rev. 2018 Oct 29;118(22):10840–11022. doi: 10.1021/acs.chemrev.8b00074

Figure 32.

Figure 32.

Cryo-reduction of heme ferric-superoxo species using γ-ray radiation at 77 K in frozen solution reported by Naruta and co-workers and its subsequent reactivity to produce the ferric-hydroperoxo adduct.