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. Author manuscript; available in PMC: 2019 Nov 28.
Published in final edited form as: Chem Rev. 2018 Oct 29;118(22):10840–11022. doi: 10.1021/acs.chemrev.8b00074

Figure 43.

Figure 43.

Porphyrinic MOF, PCN-224FeII, synthesized by Harris and co-workers (left) that reversibly binds dioxygen to give the first structurally characterized 5C low-spin heme–superoxo complex (right). Adapted from ref 534. Copyright 2014 American Chemical Society.