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. Author manuscript; available in PMC: 2019 Nov 28.
Published in final edited form as: Chem Rev. 2018 Oct 29;118(22):10840–11022. doi: 10.1021/acs.chemrev.8b00074

Figure 47.

Figure 47.

“Hangman” porphyrinate that catalyzes the disproportionation of H2O2 with the proposed intermediacy of an FeIII– OOH species that mediates proton-assisted O–O heterolysis. Adapted from ref 565. Copyright 2003 American Chemical Society.