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. Author manuscript; available in PMC: 2019 Nov 28.
Published in final edited form as: Chem Rev. 2018 Oct 29;118(22):10840–11022. doi: 10.1021/acs.chemrev.8b00074

Figure 51.

Figure 51.

Iron(III)-acylperoxo (top) and iron(III)-alkylperoxo (bottom) complexes that lead to heterolytic and homolytic O–O bond cleavage, respectively (in aqueous media), as observed by Bruice and co-workers. See text for discussion.