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. Author manuscript; available in PMC: 2019 Nov 28.
Published in final edited form as: Chem Rev. 2018 Oct 29;118(22):10840ā€“11022. doi: 10.1021/acs.chemrev.8b00074

Figure 8.

Figure 8.

Close view of the Cyt P450cam active site with the heme- bound dioxygen molecule, also highlighting the bound camphor substrate, the six coordinate oxy-heme center (as a formally FeIII- superoxide complex), and the critical H-bonding interactions involving the proximally ligated cysteine residue.