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. Author manuscript; available in PMC: 2019 Nov 28.
Published in final edited form as: Chem Rev. 2018 Oct 29;118(22):10840ā€“11022. doi: 10.1021/acs.chemrev.8b00074

Figure 9.

Figure 9.

Proposed catalytic cycle for Cyt P450 enzymes. Crystallo-graphic characterization of species 1ā€“4 has been achieved,120 while other intermediates including peroxo and hydroperoxo Cmpd I and Cmpd II have been spectroscopically observed.125,131,132 See text for details.