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. Author manuscript; available in PMC: 2019 Nov 28.
Published in final edited form as: Chem Rev. 2018 Oct 29;118(22):10840–11022. doi: 10.1021/acs.chemrev.8b00074

Figure 92.

Figure 92.

A calculated/optimized structural possibility for the OH intermediate in the reductive phase of the catalytic mechanism of O2- reduction in HCOs (Scheme 23). Φ is the displacement of the iron above the plane of the porphyrin. Figure created with data taken from ref 901.