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. Author manuscript; available in PMC: 2019 Nov 28.

Published in final edited form as: Chem Rev. 2018 Oct 29;118(22):10840–11022. doi: 10.1021/acs.chemrev.8b00074

Figure 98. — Formation of (top) end-on μ-1,2 low-spin heme–peroxo–copper adducts [(DCHIm)(F₈)Fe^III-(O₂^2–)-Cu^II(TMPA)]⁺ (LS-TMPA) and (bottom) [(DCHIm)(F₈)Fe^III-(O₂^2–)-Cuⁱⁱ(An)]⁺ (LS-AN) from their high spin precursors. Adapted from ref 497. Copyright 2015 American Chemical Society. Adapted from ref 910. Copyright 2011 American Chemical Society.