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. Author manuscript; available in PMC: 2019 Nov 28.
Published in final edited form as: Chem Rev. 2018 Oct 29;118(22):10840–11022. doi: 10.1021/acs.chemrev.8b00074

Table 2.

Product Distribution of Cyclohexanecarboxyaldehyde Deformylation Reactivity Mediated by Various Heme Iron(III)-peroxo Adducts As Reported by Watanabe and Co-workersa

percent yields of products [%]a
Entry Compound graphic file with name nihms-1001466-t0211.jpg graphic file with name nihms-1001466-t0212.jpg
1 [(TPP)FeIII-(O2)]− 15 20
2 [(TPP)FeIII-(O2)]−/PBNb 8 15
3 [(TMP)FeIII-(O2)]− trace 50
4 [(TDCPP)FeIII-(O2)]− 18 5
5 KO2 trace 40
a

Adapted with permission from ref 551. Copyright 1998 Elsevier.

b

Yield were determined by GC/MS based on peroxoiron(III) prophyrin complex used.

c

[PBN] = 10 mM (PBN: phenyl-tert- butylnitrone).