Table 2. Selected bond lengths (Å) and angles (°) for compounds 1–6 .
Compound | 1 | 2 | 3 | 4 | 5 | 6 | |
---|---|---|---|---|---|---|---|
Bond lengths | M1—X1 | 2.240 (4) | 2.588 (3) | 2.537 (1) | 2.720 (1) | 2.371 (1) | 2.658 (1) |
M1—X2 | 2.243 (4) | 2.568 (3) | 2.545 (1) | 2.710 (1) | 2.369 (1) | 2.654 (1) | |
M1—O2A | 1.985 (1) | 1.990 (10) | 2.216 (4) | 2.231 (2) | 2.259 (2) | 2.387 (5) | |
M1—O2B | 1.983 (1) | 1.990 (10) | 2.225 (4) | 2.216 (2) | 2.356 (2) | 2.378 (5) | |
Bond angles | X1—M1—X2 | 124.8 (2) | 123.7 (1) | 130.0 (1) | 130.1 (1) | 148.2 (1) | 145.1 (1) |
O1A—M1—X1 | 103.9 (3) | 104.0 (4) | 104.4 (1) | 103.7 (1) | 98.3 (1) | 102.0 (1) | |
O1A—M1—X2 | 104.0 (3) | 103.6 (4) | 103.6 (1) | 104.8 (1) | 100.4 (1) | 98.7 (1) | |
O1B—M1—X1 | 105.5 (3) | 106.2 (4) | 104.8 (1) | 102.9 (1) | 98.8 (1) | 98.6 (1) | |
O1B—M1—X2 | 102.8 (3) | 104.2 (4) | 101.9 (1) | 103.5 (1) | 100.7 (1) | 102.3 (1) | |
O1A—M1—O1B | 116.8 (4) | 115.8 (5) | 112.0 (2) | 111.6 (1) | 105.6 (1) | 105.8 (2) |