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. Author manuscript; available in PMC: 2019 Mar 19.
Published in final edited form as: Angew Chem Int Ed Engl. 2018 Mar 1;57(13):3411–3414. doi: 10.1002/anie.201800189

Figure 2.

Figure 2.

(a) Substrate-reducing activities of VnfDGKAv with VnfHAv (1) and VnfHMa (2) as the respective electron donors. The activities are calculated based on the amounts of electrons that are required for the formation of the products. Substrates and products are indicated in the figure. Percentage activities of hydrocarbon formation in the presence of CO are shown in red fonts. HCs, hydrocarbons. (b) Average electron fluxes of all substrate-reducing reactions (left) and the electron fluxes of the reactions of hydrocarbon formation from CO reduction (right) by VnfDGKAv, with VnfHAv (1) and VnfHMa (2) as the respective electron donors. (c) EPR spectra of the turnover samples of VnfDGKAv with VnfHMa (1) as the electron donor in the presence of 1 atm CO. The g values are indicated in the figure. Spectrum 2 was simulated as described in the Experimental Section and is shown below the corresponding spectrum 1.