Table 2. Comparison of the Turnover Numbers (TON) of the Different Catalystsa.
photocatalyst | rAaeUPO | CbFDH | |
---|---|---|---|
FMN | 649 | 6490 | 135 |
phenosafranine | 2500 | 25000 | 520 |
methylene blue | 3992 | 39920 | 832 |
Conditions: c(rAaeUPO) = 100 nM, c(CbFDH) = 4.8 μM, c(NAD+) = 0.4 mM, c(NaHCO2) = 75 mM, c(ethylbenzene) = 10 mM, c(photocatalyst) = 1 μM, 50 mM KPi buffer (pH 7, 0.8% MeOH (v/v)), T = 30 °C, polychromatic light source.