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. Author manuscript; available in PMC: 2020 Feb 18.
Published in final edited form as: Angew Chem Int Ed Engl. 2019 Jan 25;58(8):2371–2376. doi: 10.1002/anie.201813233

Scheme 1.

Scheme 1.

Product Diversification[a]

[a] Conditions: a) R = NHPI, Ph2Zn, Fe(acac)2, dppBz (34%); b) R = NHPI, Zn0, PhSiH3, NiCl2·6H2O (39%; c) R = Me, Mn(acac)2, PhSiH3, PPh3, O2 (64%, 2:1 dr); d) R = Me, i. NMO, OsO4; ii. (COCl)2, MeOH (65%, 6:1 dr); e) R = Me, m-CPBA (100%, 2:1 dr)