Table 1.
M.W. by GPC | M.W. calculated by 1H-NMR spectroscopy a | |||
---|---|---|---|---|
Mn | Mw | PD | ||
Me-PEG 5 k | 4390 | 5160 | 1.18 | 5000a |
PLA | 4120 | 4890 | 1.19 | 4530b |
LEse copolymer | 8210 | 9530 | 1.16 | 9530 |
PCL | 72,100 | 81,200 | 1.13 | – |
aMePEG-5 k: MePEG-NHS, M.W. = 5000 g/mol from the manufacturer. M.W. estimation of block copolymer using 1H-NMR spectroscopy was calculated based on MePEG-5 k
bM.W. of PLA was calculated from following the equation M.W. of LEse copolymer – M.W. of MePEG 5 k
Mn number-average M.W, Mw weight average M.W, PD polydispersity