. 2018 Dec 19;10(7):2193–2198. doi: 10.1039/c8sc04610g

Table 1. Ti₃–BPDC–CoH catalyzed cascade reduction of pyridines ^a .

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^a0.50 mmol pyridine, 0.525 mmol HBpin, 20 bar H₂, 0.2–0.5 mol% of Ti₃–BPDC–CoH, 100–140 °C, 22 h; yield determined by GC-MS using mesitylene as internal standard.

^bReaction time: 40 h.

^c1.05 equiv. HBpin, 35 bar H₂.

^d3 equiv. HBpin, 50 bar H₂.

^e3 equiv. HBpin, 35 bar H₂.

^f3-((Trimethylsilyl)ethynyl)pyridine as substrate, the triple bond was hydrogenated.

Table 1. Ti3–BPDC–CoH catalyzed cascade reduction of pyridines a .

Table 1. Ti₃–BPDC–CoH catalyzed cascade reduction of pyridines ^a .