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Synthesis and reactivity of “off-cycle” phenylthiophosphetanium salt 2·[SPh]+. Reaction conditions: (a) indole (1, 1.0 equiv), dioxane, rt; (b) indole (1, 1.0 equiv), PhSiH3 (2.0 equiv), dioxane, rt; (c) indole (1, 1.0 equiv), PhSiH3 (2.0 equiv), PhSO2Cl (1.8 equiv), dioxane, rt.
