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(A) Reactions of whole substrates RCH2OPO32− (kcat/Km), and substrate pieces RH + HPO32− (kcat/KHPiKd) catalyzed by OMPDC, TIM and GPDH. (B) Partitioning of the total 12 kcal/mol binding energy into the parts used for ground-state and transition-state stabilization
