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A model for OMPDC-catalyzed decarboxylation of OMP, which includes the step for loop closure over enzyme-bound OMP. (A) The limiting case where there is a large driving force for loop closure (KC > 1), so that changes in KC are expressed as changes in the kinetic parameter Km for decarboxylation of OMP. (B) The limiting case where loop closure is unfavorable (KC < 1), so that changes in KC are expressed as changes in the kinetic parameter kcat for decarboxylation of OMP.
