Table 1.

Selected bond lengths (Å) and dihedral angle (°) for Λ‐(S)/Δ‐(R)‐ax‐[4 d]PF₆.

Λ‐(S)‐ax‐[4 d]PF6
Ru1−S1	2.3311(8)	Ru1−N3	2.049(3)
Ru1−N1	2.085(3)	Ru1−N4	2.239(3)
Ru1−N2	2.060(3)	Ru1−C11	2.027(3)
S1‐C28‐C26‐N4	26.4(2)