Table 5.
Compounds | A‐C | A‐PCS | P‐C | P‐PCS | NT‐C | NT‐PCS |
---|---|---|---|---|---|---|
1‐Propanol, 2‐methyl | 0.12 ± 0.01b | 0.11 ± 0.01b | 0.10 ± 0.01b | 0.19 ± 0.03a | 0.13 ± 0.01b | 0.15 ± 0.01ab |
1‐Butanol, 3‐methyl | 3.88 ± 0.10d | 4.49 ± 0.17ab | 4.12 ± 0.07c | 4.52 ± 0.24ab | 4.33 ± 0.07b | 4.73 ± 0.12a |
1‐Pentanol, 3‐methyl‐ | 0.01 ± 0.01 | 0.01 ± 0.01 | ND | ND | 0.01 ± 0.01 | ND |
1‐Hexanol | 0.08 ± 0.01c | 0.06 ± 0.01c | 0.11 ± 0.01b | 0.06 ± 0.02c | 0.11 ± 0.01b | 0.18 ± 0.01a |
1‐Hexanol, 2‐ethyl‐ | 0.01 ± 0.01 | 0.01 ± 0.01 | 0.02 ± 0.01 | 0.03 ± 0.01 | 0.02 ± 0.01 | 0.01 ± 0.01 |
Phenylethyl alcohol | 0.94 ± 0.01c | 0.92 ± 0.09c | 1.36 ± 0.22a | 1.25 ± 0.15a | 0.94 ± 0.04c | 1.07 ± 0.01b |
Total alcohols | 5.04 ± 0.11c | 5.60 ± 0.10b | 5.71 ± 0.14b | 6.05 ± 0.16a | 5.54 ± 0.11b | 6.14 ± 0.14a |
Ethyl acetate | 0.65 ± 0.02b | 0.54 ± 0.04c | 0.55 ± 0.06c | 0.83 ± 0.12a | 0.57 ± 0.04c | 0.63 ± 0.04bc |
Ethyl isobutyrate | 0.02 ± 0.01 | 0.02 ± 0.01 | 0.02 ± 0.01 | 0.02 ± 0.01 | 0.01 ± 0.01 | 0.01 ± 0.01 |
Ethyl isovalerate | 0.04 ± 0.01 | 0.03 ± 0.01 | 0.02 ± 0.01 | 0.05 ± 0.03 | 0.02 ± 0.01 | 0.02 ± 0.01 |
Ethyl butyrate | 0.03 ± 0.01 | 0.04 ± 0.01 | 0.04 ± 0.01 | 0.05 ± 0.02 | 0.02 ± 0.01 | 0.02 ± 0.01 |
Isoamyl acetate | 0.20 ± 0.02b | 0.46 ± 0.05a | 0.20 ± 0.02b | 0.46 ± 0.05a | 0.28 ± 0.07b | 0.49 ± 0.05a |
Ethyl 2‐methylbutyrate | 0.03 ± 0.01 | 0.01 ± 0.01 | ND | ND | 0.01 ± 0.01 | 0.01 ± 0.01 |
Ethyl hexanoate | 0.49 ± 0.04bc | 0.69 ± 0.12a | 0.50 ± 0.01b | 0.61 ± 0.11a | 0.44 ± 0.03c | 0.61 ± 0.11a |
Ethyl heptanoate | 0.01 ± 0.01 | 0.01 ± 0.01 | ND | ND | 0.01 ± 0.01 | ND |
Ethyl octanoate | 1.57 ± 0.08b | 2.10 ± 0.11a | 1.65 ± 0.12b | 2.16 ± 0.16a | 1.20 ± 0.22c | 1.60 ± 0.13b |
Ethyl decanoate | 0.28 ± 0.02c | 0.37 ± 0.04b | 0.40 ± 0.03b | 0.48 ± 0.03a | 0.21 ± 0.06c | 0.36 ± 0.01b |
Diethyl succinate | 0.36 ± 0.01a | 0.37 ± 0.02a | 0.29 ± 0.02b | 0.19 ± 0.06c | 0.10 ± 0.01d | 0.27 ± 0.01b |
Ethyl phenylacetate | 0.01 ± 0.01 | 0.01 ± 0.01 | ND | ND | 0.01 ± 0.01 | 0.01 ± 0.01 |
Total esters | 3.69 ± 0.21b | 4.65 ± 0.22a | 3.67 ± 0.22b | 4.85 ± 0.37a | 2.88 ± 0.31c | 4.03 ± 0.26b |
Acetic acid | 0.04 ± 0.01ab | 0.03 ± 0.01ab | 0.06 ± 0.01a | 0.06 ± 0.02a | 0.02 ± 0.01b | 0.05 ± 0.01a |
Hexanoic acid | 0.01 ± 0.01 | 0.01 ± 0.01 | ND | ND | ND | 0.01 ± 0.01 |
Octanoic acid | 0.03 ± 0.01 | 0.04 ± 0.01 | 0.02 ± 0.01 | 0.02 ± 0.01 | 0.02 ± 0.01 | 0.03 ± 0.01 |
Total acids | 0.08 ± 0.01a | 0.08 ± 0.01a | 0.08 ± 0.02a | 0.08 ± 0.02a | 0.04 ± 0.01b | 0.09 ± 0.01a |
Nonanal | ND | ND | ND | ND | ND | 0.01 ± 0.01 |
Furfural | 0.01 ± 0.01 | 0.01 ± 0.01 | ND | ND | 0.02 ± 0.01 | 0.02 ± 0.01 |
Total aldehydes | 0.01 ± 0.01 | 0.01 ± 0.01 | ND | ND | 0.02 ± 0.01 | 0.03 ± 0.01 |
Total contents | 8.82 ± 0.27b | 10.34 ± 0.25a | 9.46 ± 0.15b | 10.98 ± 0.48a | 8.48 ± 0.30c | 10.29 ± 0.40a |
A‐C, Aglianico control; A‐PCS, Aglianico prefermentative cold soak; P‐C, Primitivo control; P‐PCS, Primitivo prefermentative cold soak; NT‐C, Nero di Troia control; NT‐PCS, Nero di Troia prefermentative cold soak. In rows, data followed by different letters indicate statistically significant differences at p < 0.05. ND, not detected.