Table 2.
Compounds | D.F. (%) |
Med | Min | Max | WB 1 | WB 2 | WB 3 | WB 4 | WB 5 | WB 6 | WB 7 | WB 8 | WB 9 | WB 10 |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Polybrominated diphenyl ethers (PBDEs) | ||||||||||||||
BDE-17 | 100 | 0.19 | 0.09 | 1.94 | 0.09 | 0.61 | 0.31 | 0.10 | 0.11 | 0.76 | 0.13 | 1.94 | 0.25 | 0.13 |
BDE-28 | 100 | 0.80 | 0.26 | 7.16 | 0.26 | 2.11 | 1.45 | 0.44 | 0.58 | 3.97 | 0.69 | 7.16 | 0.90 | 0.43 |
BDE-47 | 100 | 27.3 | 6.11 | 200 | 6.11 | 73.8 | 46.7 | 11.5 | 14.5 | 132 | 16.1 | 200 | 38.5 | 13.1 |
BDE-49 | 100 | 2.03 | 0.39 | 7.80 | 0.39 | 5.24 | 2.05 | 1.00 | 0.98 | 5.46 | 2.00 | 7.80 | 5.08 | 0.70 |
BDE-66 | 100 | 0.71 | 0.12 | 4.88 | 0.12 | 2.03 | 1.00 | 0.28 | 0.33 | 3.15 | 0.42 | 4.88 | 1.02 | 0.24 |
BDE-71 | 62 | 0.46 | <0.10 | 2.36 | <0.10 | 1.55 | 0.40 | 0.43 | <0.10 | 0.26 | <0.10 | 0.48 | 2.36 | <0.10 |
BDE-85 | 100 | 0.77 | 0.14 | 2.78 | 0.14 | 2.06 | 1.08 | 0.30 | 0.34 | 1.58 | 0.47 | 2.78 | 1.07 | 0.25 |
BDE-99 | 100 | 18.4 | 3.52 | 87.9 | 3.52 | 49.1 | 28.6 | 7.84 | 9.52 | 52.4 | 11.2 | 87.9 | 25.6 | 8.13 |
BDE-100 | 100 | 3.47 | 0.68 | 20.7 | 0.68 | 9.41 | 5.75 | 1.43 | 1.78 | 12.6 | 2.01 | 20.7 | 4.94 | 1.52 |
BDE-119 | 100 | 0.28 | 0.15 | 0.56 | 0.28 | 0.42 | 0.53 | 0.15 | 0.44 | 0.24 | 0.27 | 0.56 | 0.25 | 0.15 |
BDE-126 | 77 | 0.13 | <0.07 | 0.39 | <0.07 | 0.23 | 0.10 | <0.07 | <0.07 | 0.25 | 0.07 | 0.39 | 0.13 | 0.08 |
BDE-153 | 100 | 1.36 | 0.22 | 4.06 | 0.22 | 3.54 | 1.79 | 0.59 | 0.62 | 4.06 | 1.12 | 3.99 | 1.61 | 0.54 |
BDE-154 | 92 | 1.03 | <0.24 | 2.93 | <0.24 | 2.24 | 1.12 | 0.36 | 0.39 | 1.91 | 0.64 | 2.93 | 1.03 | 0.34 |
BDE-180 | 69 | 0.34 | <0.06 | 0.92 | <0.06 | 0.73 | 0.07 | <0.06 | 0.34 | 0.92 | 0.10 | 0.51 | 0.07 | <0.06 |
BDE-183 | 62 | 0.28 | <0.20 | 7.91 | <0.20 | 0.28 | 0.26 | <0.20 | <0.20 | 7.91 | 0.18 | 1.41 | 0.27 | <0.20 |
BDE-196 | 54 | 1.24 | <0.13 | 3.52 | <0.13 | <0.13 | 0.43 | <0.13 | <0.13 | 3.52 | <0.13 | 1.08 | 1.40 | <0.13 |
BDE-197 | 100 | 0.22 | <0.09 | 5.14 | <0.09 | 0.33 | 0.22 | 0.10 | <0.09 | 5.14 | 0.11 | 0.69 | 0.23 | 0.12 |
BDE-206 | 100 | 1.08 | <0.26 | 10.5 | <0.26 | 2.67 | 0.80 | 0.88 | 0.96 | 10.5 | 1.08 | 3.94 | 0.86 | 1.98 |
BDE-207 | 92 | 0.82 | <0.39 | 3.50 | <0.39 | 1.02 | 0.54 | <0.39 | 0.39 | 3.50 | 0.59 | 2.47 | 0.62 | 1.14 |
BDE-209 | 100 | 15.6 | 5.90 | 61.0 | 16.6 | 15.7 | 5.90 | 15.4 | 15.2 | 47.2 | 12.9 | 61.0 | 13.3 | 24.7 |
∑BDEs | 76.3 | 28.4 | 412 | 28.4 | 173 | 99.1 | 40.8 | 46.5 | 297 | 50.2 | 412 | 99.4 | 53.4 | |
New Flame Retardants (NFRs) | ||||||||||||||
PBBZ | 92 | 0.24 | <0.09 | 2.39 | <0.09 | 0.55 | 0.10 | 0.37 | 0.21 | 0.11 | 0.20 | 0.37 | 2.39 | 0.24 |
PBEB | 85 | 0.19 | <0.06 | 0.36 | 0.08 | 0.28 | 0.04 | <0.06 | 0.27 | 0.20 | 0.13 | 0.19 | 0.36 | 0.04 |
HBB | 100 | 0.19 | 0.07 | 1.50 | 0.07 | 1.50 | 0.11 | 0.09 | 0.34 | 0.16 | 0.11 | 0.37 | 0.21 | 1.37 |
EHTBB | 100 | 89.1 | 15.4 | 358 | 15.4 | 358 | 103 | 87.8 | 32.0 | 42.5 | 116 | 90.5 | 263 | 16.3 |
TBE | 85 | 0.33 | <0.07 | 5.70 | 0.13 | 2.94 | 0.10 | 0.07 | 0.24 | 4.03 | 0.33 | 5.70 | 0.45 | <0.07 |
BEHTBP | 85 | 193 | <0.26 | 354 | 25.0 | 193 | 303 | 64.4 | 48.5 | 354 | 199 | 265 | 114 | <0.26 |
Syn-DP | 69 | 0.81 | <0.32 | 2.17 | <0.32 | 0.94 | <0.32 | <0.32 | <0.32 | 0.68 | 1.03 | 2.17 | 0.47 | 0.60 |
Anti-DP | 69 | 2.08 | <0.65 | 11.5 | <0.65 | 2.27 | <0.65 | <0.65 | <0.65 | 5.71 | 0.68 | 11.5 | <0.65 | 1.88 |
DBDPE | 92 | 10.3 | <0.26 | 66.0 | <0.26 | 66.0 | 1.06 | 5.45 | 10.3 | 8.36 | 10.5 | 31.1 | 4.53 | 62.3 |
∑NFRs | 356 | 40.7 | 625 | 40.7 | 625 | 407 | 158 | 91.9 | 415 | 327 | 407 | 385 | 82.7 | |
Organophosphate esters (OPEs) | ||||||||||||||
TEP | 54 | 96.7 | <26.7 | 1720 | <26.7 | 90.8 | <26.7 | 96.7 | <26.7 | 113 | <26.7 | 1720 | 35.2 | <26.7 |
TPRP | 62 | 156 | <10.9 | 273 | 156 | <10.9 | <10.9 | 59.8 | <10.9 | <10.9 | <10.9 | 170 | 273 | 31.6 |
TNBP | 77 | 93.1 | <25.0 | 881 | 37.8 | 87.4 | <25.0 | 56.4 | 53.4 | 166 | 881 | 98.9 | 129 | <25.0 |
TCEP | 100 | 60.9 | 27.2 | 348 | 27.2 | 60.2 | 118 | 28.2 | 54.9 | 114 | 54.4 | 211 | 61.6 | 348 |
TCIPP | 100 | 288 | 109 | 1050 | 109 | 420 | 286 | 205 | 1050 | 199 | 289 | 191 | 440 | 433 |
TDCIPP | 100 | 759 | 168 | 2060 | 340 | 1620 | 2060 | 766 | 184 | 752 | 168 | 2030 | 1480 | 257 |
TPHP | 100 | 290 | 72.1 | 1360 | 157 | 961 | 192 | 300 | 72.1 | 442 | 161 | 1360 | 878 | 279 |
TBOEP | 100 | 2090 | 878 | 4000 | 1500 | 1240 | 878 | 4000 | 1550 | 3350 | 2090 | 2090 | 2220 | 2270 |
EHDP | 85 | 245 | <56.0 | 979 | 78.4 | 273 | 542 | <56.0 | <56.0 | 979 | 165 | 414 | 217 | 199 |
TEHP | 77 | 353 | <6.25 | 710 | <6.25 | 510 | 167 | 516 | 115 | 412 | 710 | 295 | 268 | <6.25 |
TMTP | 85 | 41.1 | <2.50 | 433 | 37.8 | 54.0 | 139 | 23.4 | 12.0 | 41.1 | 23.5 | 433 | 285 | <2.50 |
TIPPP | 54 | 31.9 | <1.00 | 3400 | <1.00 | 3400 | 24.7 | <1.00 | 33.9 | 29.8 | 13.2 | <1.00 | <1.00 | 58.5 |
TDMPP | 54 | 44.9 | <8.62 | 144 | <8.62 | <8.62 | <8.62 | <8.62 | <8.62 | 39.6 | <8.62 | 29.9 | 50.2 | 144 |
TDBPP | 54 | 3025 | <100 | 3520 | <100 | <100 | 3190 | 2990 | 2060 | 3060 | 3520 | <100 | <100 | 1040 |
∑OPEs | 7840 | 2440 | 9580 | 2440 | 8620 | 7600 | 8960 | 5220 | 9580 | 8080 | 9040 | 6340 | 5060 | |
Polycyclic aromatic hydrocarbons (PAHs) | ||||||||||||||
Acenaphthylene | 100 | 4.46 | 2.59 | 7.94 | 2.59 | 7.94 | 4.39 | 4.37 | 4.97 | 3.46 | 3.42 | 6.39 | 4.53 | 5.88 |
Acenaphthene | 62 | 10.7 | <5.21 | 30.2 | <5.21 | 13.3 | 8.31 | <5.21 | <5.21 | <5.21 | <5.21 | 30.2 | 13.1 | 6.29 |
Fluorene | 100 | 24.3 | 10.8 | 102 | 15.3 | 36.1 | 18.1 | 31.1 | 18.2 | 16.5 | 102 | 37.7 | 30.4 | 10.8 |
Phenanthrene | 100 | 89.3 | 21.4 | 336 | 30.3 | 148 | 81.0 | 71.7 | 27.4 | 153 | 336 | 235 | 97.7 | 21.4 |
Anthracene | 69 | 64.2 | <0.57 | 106 | 7.10 | 85.5 | <0.57 | <0.57 | <0.57 | <0.57 | 93.3 | 106 | 37.5 | 43.0 |
Fluoranthene | 100 | 30.0 | 9.22 | 198 | 11.6 | 106 | 17.8 | 18.4 | 9.22 | 57.9 | 198 | 195 | 41.6 | 17.2 |
Pyrene | 100 | 29.9 | 8.46 | 274 | 19.6 | 79.0 | 14.5 | 19.9 | 11.8 | 159 | 149 | 274 | 40.0 | 8.46 |
Benz[a]anthracene | 100 | 16.0 | 0.36 | 212 | 4.52 | 39.2 | 21.6 | 36.9 | 2.95 | 81.8 | 24.6 | 212 | 131 | 0.36 |
Chrysene | 77 | 19.4 | <2.14 | 143 | <2.14 | 29.3 | 2.76 | 2.45 | 1.67 | 66.6 | 27.4 | 143 | <2.14 | 11.4 |
∑PAHs | 273 | 76.2 | 1240 | 95.3 | 544 | 168 | 185 | 76.2 | 538 | 934 | 1240 | 395 | 125 |