Table 1. Annotated compounds found in the HD bioactive fractions 5 and 7 of R. idaeus (var Prestige) in positive and negative modes using a Thermo Orbitrap XL LC-MS.

Additionally, the presence (+) or absence (−) of compounds in the fractions is noted.

Retention Time (min)	m/z		Molecular Formula	Tentative Identification	Identity Level	Fractions
	Positive Mode	Negative Mode				5	7
8.93	—	343.1029 [M-H]−	C15H20O9	Methoxybenzoyl-hexoside	3	+	—
9.17	—	299.0769 [M-H]−	C13H16O8	Hydroxy-benzoyl-hexoside isomer A	3	+	—
		375.0928	—	Unknown	4	+	—
9.31	332.1354 [M+NH4]+	313.0923 [M-H]−	C14H18O8	Hydroxyphenylacetate-hexoside	3	+	—
		359.0976 [M+FA-H]−
10.10	205.0977 [M+H]+	203.0825 [M-H]−	C11H12N2O2	Trp	1	+	—
10.45	—	357.1186 [M+FA-H]−	C15H20O7	Phenylpropanoyl-hexoside	3	+	—
		143.0350	—	Unknown	4	+	—
10.55	—	299.1132 [M-H]−	C14H18O8	Salidroside	1	+	—
		345.1184 [M+FA-H]−
10.72	—	341.0874 [M-H]−	C15H18O9	Caffeoyl-glucoside	2	+	—
11.03	—	427.1239 [M-H]−	C19H24O11	Unknown	4	+	—
11.08	—	299.0768 [M-H]−	C13H16O8	Hydroxy-benzoyl-hexoside isomer B	3	+	—
		355.0666 [M-H]−	C15H16O10	Coumaroyl-quinic acid	2	+	—
11.41	464.1780 [M+NH4]+	445.1342 [M-H]−	C19H26O12	Benzoyl-dihexoside isomer A	3	+	—
	469.1333 [M+Na]+
11.65	—	445.1346 [M-H]−	C19H26O12	Benzoyl-dihexoside isomer B	3	+	—
11.73	611.1619 M+	609.1446 [M+-2H]−	C27H31O16+	Cyanidin 3-O-sophoroside	1	—	+
12.00	757.2214 M+	755.2022 [M+-2H]−	C33H41O20+	Cyanidin di-hexoside rhamnosyl	2	—	+
12.19	449.1098 M+	447.0928 [M+-2H]−	C15H11O6+	Cyanidin 3-O-glucoside	1	—	+
12.37	595.1672 M+	593.1499 [M+-2H−	C27H31O15+	Cyanidin 3-O-rutinoside	1	—	+
12.40	629.174 [M+H]+	627.1552 [M-H]−	C15H12O7	Taxifolin di-hexoside	3	—	+
12.62	—	439.1815	—	Unknown	4	—	+
		523.1812	—	Unknown	4	—	+
		623.2181	—	Unknown	4	—	+
12.66	808.2535 [M+NH4]+	789.2075 [M-H]−	C33H42O22	Unknown	4	—	+
12.67	231.114	—	—	Unknown	4	+	—
	302.1249	—	—	Unknown	4	+	—
	—	329.0873	—	Unknown	4	+	—
	—	577.1344	—	Unknown	4	+	—
	—	283.0821	—	Unknown	4	+	—
12.72	467.1197 [M+H]+	465.1031 [M-H]−	C21H22O12	Taxifolin-hexoside	3	—	+
12.78	544.2408 [M+NH4]+	—	C25H34O12	Unknown	4	—	+
12.99	317.1391 [M+H]+	—	C18H20O5	Unknown	4	—	+
13.10	—	385.1135 [M-H]−	C17H22O10	Sinapoyl-hexoside	3	—	+
	—	475.1451 [M-H]−	C20H28O13	Hydroxyphenylacetate-dihexoside	4	—	+
13.15	434.2035 [M+NH4]+	461.1656 [M+FA-H]−	C19H28O10	Benzyl alcohol-rutinoside	3	—	+
13.22	464.1781 [M+NH4]+	445.1348 [M-H]−	C19H26O12	Benzoyl di-hexoside isomer C	3	+	—
		491.1401 [M+FA-H]−
	267.067	—	—	Unknown	4	+	—
13.40	291.0873 [M+H]+	289.0712 [M-H]−	C15H14O6	(−)-epicatechin	1	—	+
13.56	—	571.2025 [M-H]−	C26H36O14	Unknown	4	—	+
13.70	—	299.0770 [M-H]−	C13H16O8	Unknown	4	—	+
		401.1444	—	Unknown	4	—	+
		445.1347 [M-H]−	C19H26O12	Benzoyl di-hexoside isomer D	3	—	+
		491.1400[M+FA-H]−
14.11	—	783.0662 [M-2H]2−	C68H48O44	Sanguiin H-10;	2	—	+
		1401.6058 [M-2H]2−	C123H80O78	Lambertianin C	2	—	+
14.16	—	371.0975 [M-H]−	C16H20O10	Unknown	4	—	+
14.40	—	934.0682 [M-2H]2−	C82H54O52	Sanguiin H-6	2	—	+
14.80	—	455.1761 [M+FA-H]−	C17H30O11	Unknown	4	—	+
14.82	—	859.071 [M-2H]2−	C75H52O48	Unknown Tannin	3	—	+