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. 2019 Feb 28;9:3169. doi: 10.1038/s41598-019-39357-1

Table 1.

Hydrogen, nitrogen and carbon isotopic and elemental ratios of organic matter (OM) aggregate and matrix of the Zag clast measured by NanoSIMS.

δD ‰ δ15N ‰ δ13C ‰ H/C N/C O/Ca
OM aggregate 2,370 ± 74 696 ± 100 −43 ± 20 0.6 ± 0.1 0.022 ± 0.004 (0.06–0.07) ± 0.02
Hot spot #1 4,200 ± 550 3,413 ± 1,070 0.4 ± 0.1 0.032 ± 0.006
Hot spot #2 4,500 ± 900 724 ± 780
Matrix 301 ± 98 10 ± 41 0.036 ± 0.007 ~1.4–1.6
CI IOMb 972–978 30.7–31.9 −17.1 to −17.0 0.67–0.72 0.035–0.035 0.18–0.15
CM IOM (except Bells)b 639–893 −8.5 to +7.5 −18.9 to 17.1 0.52–0.70 0.026–0.037 0.11–0.23
Bells IOM (Anomalous CM)b 3283 415 −34.2 0.63 0.034 0.21
CR IOMb 2,619–3,527 162–309 −26.6 to −20.3 0.69–0.81 0.032–0.044 0.11–0.22
Ordinary chondrite IOMb 1,917–6,181 −39 to +36 −23.7 to −10.4 0.16–0.48 <0.019 0.14–0.29
Tagish Lake IOMc 596 to 1,844 53 to 73 −14.7 to −13.3 0.34–0.72 0.041–0.043 0.13–0.26
Comets up to ~2,200d ~400–1200e 0.035 ± 0.011f

aThe upper limits estimated by C,N,O K-edge X-ray absorption spectra. Note that N/C ratio is too low to be estimated by XANES.

bInsoluble organic matter (IOM) data from Alexander et al.18.

cIOM data from Herd et al.42 and Alexander et al.41.

dCometary water data from Altwegg et al.35 and references therein.

eData from Marty19 and references therein.

fData from Fray et al.29.