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Chlorobenzene amination as modeled at the B3LYP-XDM/6-311+G(2d,2p)//B3LYP-XDM/6-31+G*&6-31G* level of theory: (a) Ni(0)/Ni(II) cycle, fast OA and slow RE; (a) Ni(I)/Ni(III), slow OA and fast RE. Adapted with permission from ref (624). Copyright 2017 Wiley-VCH.
