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. 2019 Jan 31;141(8):3320–3331. doi: 10.1021/jacs.8b10836

Scheme 2. OMPDC-Catalyzed Decarboxylation, with an 8 kcal/mol Stabilization of the Ground-State Complex (Kd = 10–6 M) and a 31 kcal/mol Stabilization of the Rate-Determining Transition State (Kd⧧ = 10–23 M)44,45.

Scheme 2