Table 1.
POSS filler | PF | P3HT | ||||
---|---|---|---|---|---|---|
Δλabs (nm) b | Δλem (nm) c | ΦPL (%) d,e | Δλabs (nm) f | Δλem (nm) g | ΦPL (%) e,h | |
(iC4 + CP) | −16 | +3 | +3 | +22 | +20 | +1.1 |
(iC4 + C18) | −21 | +3 | +6 | +26 | +30 | +1.5 |
(CP + C18) | −15 | +3 | +6 | +27 | +24 | +1.4 |
iC4&CP | −16 | +4 | +6 | +24 | +27 | +1.3 |
iC4&C18 | −11 | +2 | +6 | +24 | +27 | +1.5 |
CP&C18 | −8 | +1 | +6 | +24 | +25 | +1.7 |
a 40 wt % heterogeneous POSS and mixture with 20 wt % each POSS. b Determined with the peak at 407 nm. c Determined with the peak at 509 nm (λex = 407 nm). d Compared with 41% from the pristine polymer. e Determined as an absolute value with the integration sphere method. f Determined with the peak at 484 nm. g Determined with the peak at 639 nm (λex = 484 nm). h Determined with 0.7% from the pristine polymer.