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. 2018 Dec 29;11(1):44. doi: 10.3390/polym11010044

Table 1.

Optical property changes by hybrid formation with POSS a.

POSS filler PF P3HT
Δλabs (nm) b Δλem (nm) c ΦPL (%) d,e Δλabs (nm) f Δλem (nm) g ΦPL (%) e,h
(iC4 + CP) −16 +3 +3 +22 +20 +1.1
(iC4 + C18) −21 +3 +6 +26 +30 +1.5
(CP + C18) −15 +3 +6 +27 +24 +1.4
iC4&CP −16 +4 +6 +24 +27 +1.3
iC4&C18 −11 +2 +6 +24 +27 +1.5
CP&C18 −8 +1 +6 +24 +25 +1.7

a 40 wt % heterogeneous POSS and mixture with 20 wt % each POSS. b Determined with the peak at 407 nm. c Determined with the peak at 509 nm (λex = 407 nm). d Compared with 41% from the pristine polymer. e Determined as an absolute value with the integration sphere method. f Determined with the peak at 484 nm. g Determined with the peak at 639 nm (λex = 484 nm). h Determined with 0.7% from the pristine polymer.