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. 2018 Oct 11;10(10):1129. doi: 10.3390/polym10101129

Table 3.

Selected examples of applications and relevant features for several polymer–inorganic oxide nanocomposites.

Application Nanocomposite System Features Reference
Electrical insulation Epoxy–SiO2
Epoxy–TiO2
Increased dielectric breakdown strength
Decreased complex permittivity
Increased Tg
Increased strength, toughness, ductility
[16,18,108,116,117,118,119,120]
PE 1–MgO
PE–Al2O3
Decreased DC conductivity
Increased dielectric breakdown strength
Decreased space charge accumulation
Decreased complex permittivity
[121,122,123,124,125]
PI 2–SiO2 Decreased electrical conductivity
Increased scratch hardness
Increased strength
[126]
Fuel cells Nafion–TiO2
Nafion–SiO2
Increased water uptake
Decreased resistivity
Increased Tg
Increased degradation temperature
[105,127,128]
PVA 3–SiO2 Increased liquid retention
Increased proton conductivity
Higher ion-exchange capacity
[129,130]
PVDF 4–Al2O3 High proton conductivity
High thermal stability
Low methanol permeability
Increased water uptake
[131]
Coatings Epoxy–SiO2 Increased flame retardance
High Tg
Good thermal stability
[132]
PDMS–TiO2–SiO2 Transparent and hydrophobic
Increased hardness
[68]
Epoxy–SiO2
Epoxy–Fe2O3
Improved corrosion resistance
Increased Young’s modulus
[133]
PDMS–PVA–ZnO Decreased hydrophobicity
Reduced contamination by fluorescent biomarkers in biosensors
[134]
Epoxy–PANI 5–ZnO Antifouling and antibacterial properties [135]
Bioactive materials PDMS–CaO–SiO2–TiO2 Increased Young’s modulus
High apatite-forming ability
High extensibility
High strength
[33,111]
PDMS–CaO–SiO2 High apatite-forming ability
Decreased release of silicon in body fluids
Mechanical properties analogous to those of human cancellous bones
[110]
Solid electrolytes PEO 6–SiO2 Increased Li+ transference number
Increased Tg
[88]
PEG–PU/PAN 7 with TiO2 Good thermal stability
Increased ionic conductivity
[114]
Ultrafiltration PS8–TiO2 Increased hydrophilicity
Increased permeability
Increased Tg
[101]
Electromagnetic interference shielding (EMI) PANI–SiO2 Increased EMI shielding effectiveness
Increased thermal stability
[93]

1 Polyethylene; 2 Polyimide; 3 Poly(vinyl acetate); 4 Poly(vinylidene fluoride); 5 Polyaniline; 6 Poly(ethylene oxide); 7 Poly(ethylene glycol) –polyurethane/poly(acrylonitrile); 8 Polystyrene.