Table 2.

Synthesis results of N₃-PCL_n-C≡CH precursors and their c-PCL_n products.

Polymer	Yield a (%)	Mn,theo b (g/mol)	${\overline{{\mathit{M}}_{\mathit{n},}}}_{\mathit{N}\mathit{M}\mathit{R}}$ c (g/mol)	${\overline{{\mathit{M}}_{\mathit{n},}}}_{\mathit{G}\mathit{P}\mathit{C}}$ d (g/mol)	PDI e
N3-PCL20-C≡CH	96.8	2530	2770	2700	1.10
c-PCL20	37.7	2540	2790	2300	1.07
N3-PCL30-C≡CH	97.7	3690	4000	5000	1.09
c-PCL30	38.1	3700	4100	3700	1.09
N3-PCL50-C≡CH	97.2	5990	6340	7700	1.06
c-PCL50	37.9	6000	6350	5200	1.07
N3-PCL70-C≡CH	97.5	8300	7950	11,100	1.08
c-PCL70	39.5	8300	8000	7900	1.10
N3-PCL90-C≡CH	98.1	10,600	10,200	13,000	1.10
c-PCL90	38.9	10,700	10,200	9500	1.08
N3-PCL100-C≡CH	96.8	11,700	11,900	16,400	1.10
c-PCL100	40.2	11,800	12,000	12,100	1.06
N3-PCL150-C≡CH	97.5	17,500	17,200	20,800	1.11
c-PCL150	40.5	17,500	17,300	15,300	1.13
N3-PCL200-C≡CH	97.6	23,200	23,200	26,800	1.13
c-PCL200	41.1	23,300	23,200	21,500	1.11

^a Reaction yield. ^b Molecular weight estimated from the theoretical molecular weights of N₃-PCL_n-OH precursors in Table 1. ^c Number-average molecular weight determined by ¹H NMR spectroscopy analysis. ^d Number-average molecular weight determined THF by using GPC analysis calibrated with polystyrene (PS) standards. ^e Polydispersity index determined by using GPC analysis calibrated with PS standards.