Table 2.
Interaction mechanism and the main properties of systems of pectin with different components.
Components | Interaction Mechanism | The Main Properties of the Complex | References |
---|---|---|---|
Avicel cellulose | By pectin side chains—arabinans and galactans; possible formation of hydrogen bonds | Low reversibility of complex | [116] |
Sugar-beet microfibrillated cellulose | By pectin side chains | Enhancement of viscoelastic properties of cellulose suspension | [118] |
Ferulic acid/protein | Covalently linked to pectin side chains, mainly to arabinose and galactose residues (in sugar beet cell wall) | Improvement in emulsifying ability and stability, surface activity of sugar beet pectins | [131] |
Protein | Maillard reaction: carbonyl group of a reducing sugar residue of pectin reacting with an amino group of protein | Changes in solubility; amphiphilic character; high molecular weight; better emulsification properties | [136] |
Starch | possible enhancement of pectin network through ionic interactions | Increase in the viscoelasticity, values of starch pasting parameters and extrusion parameters | [144,145] |
Chitosan | Formation of a polyelectrolyte complex: electrostatic interaction between oppositely charged groups (pectin: COO−, chitosan: NH3+); other possible interactions: hydrogen bonds, coordinate bonds, van der Waals interactions and hydrophobic forces | Homogeneous PEC films; degradation of PEC films at lower temperature than decomposition of chitosan (thermogravimetric analysis) | [147,148] |
Chitosan + calcium ions or NHS/EDC | Calcium ions as crosslinking agents of pectins; NHS/EDC: formation of covalent bonds between pectin and chitosan | Higher tensile strength of membranes and lower water uptake ability | [153] |