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. 2018 Jul 11;10(7):762. doi: 10.3390/polym10070762

Table 2.

Interaction mechanism and the main properties of systems of pectin with different components.

Components Interaction Mechanism The Main Properties of the Complex References
Avicel cellulose By pectin side chains—arabinans and galactans; possible formation of hydrogen bonds Low reversibility of complex [116]
Sugar-beet microfibrillated cellulose By pectin side chains Enhancement of viscoelastic properties of cellulose suspension [118]
Ferulic acid/protein Covalently linked to pectin side chains, mainly to arabinose and galactose residues (in sugar beet cell wall) Improvement in emulsifying ability and stability, surface activity of sugar beet pectins [131]
Protein Maillard reaction: carbonyl group of a reducing sugar residue of pectin reacting with an amino group of protein Changes in solubility; amphiphilic character; high molecular weight; better emulsification properties [136]
Starch possible enhancement of pectin network through ionic interactions Increase in the viscoelasticity, values of starch pasting parameters and extrusion parameters [144,145]
Chitosan Formation of a polyelectrolyte complex: electrostatic interaction between oppositely charged groups (pectin: COO, chitosan: NH3+); other possible interactions: hydrogen bonds, coordinate bonds, van der Waals interactions and hydrophobic forces Homogeneous PEC films; degradation of PEC films at lower temperature than decomposition of chitosan (thermogravimetric analysis) [147,148]
Chitosan + calcium ions or NHS/EDC Calcium ions as crosslinking agents of pectins; NHS/EDC: formation of covalent bonds between pectin and chitosan Higher tensile strength of membranes and lower water uptake ability [153]