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ROMP of 7-oxonorbornene derivative 13 with β-barrel engineered artificial metalloenzymes.a
 | ||||
| entry | catalyst | conversionb (%) | TON | PDIc |
| 1 | ArM 5 | 25 | 3000 | 1.29 |
| 2 | ArM 6 | 81 | 10000 | 1.21 |
| 3 | ArM 7 | 75 | 9300 | 1.29 |
| 4 | 9 | 16 | 1700 | N.D. |
a[13] = 0.2 M. bDetermined by 1H NMR spectroscopy. cPDI = polydispersity index.
