Table 11.

Selected CM results with cavity-size engineered ArMs.

entrya	catalyst	substrate	conversionb (%)	TON
1	ArM 5	73	>99c	100
2	ArM 6	73	>99c	100
3	ArM 7	73	69c	69
4	9	73	79c	79
5	9 + NB4exp	73, 74, 75	0	0
6	ArM 5	74	45c	45
7	ArM 6	74	>99c	100
8	ArM 7	74	>99c	100
9	9	74	98d	98
10	ArM 5	75	40d	40
11	ArM 6	75	>99d	100
12	ArM 7	75	>99d	100
13	9	75	94d	94

^a[Substrate] = 0.05 M. ^bConversions determined by ¹H NMR. ^cE/Z = 20:1. ^dE/Z = 99:1.