Figure 9.

Internal structure of cylindrical micelles can be semicrystalline, glassy, or amorphous. (A) Pyrene release from glassy micelles occurs around and above the T_g of the core block. Reproduced with permission from ref (62). Copyright 2011 Wiley. (B) TEM confirms the crystallinity of cylindrical micelles produced by CDSA. Reproduced with permission from ref (19). Copyright 2017 American Chemical Society. (C) Unlike cylindrical micelles, bottlebrush polymers most likely do not possess an internal hydrophobic compartment.